Some interesting ash cloud lightning captured in HD in the evening of April 17th 2010 facing Eyjafjallajokull. Underneath an animated gif from the 11 frames that contained the strike in slow motion. A HD video can be watched here, the strike occurs around 23 seconds…
Volcanic ash consists of small tephra, which are bits of pulverized rock and glass created by volcanic eruptions, less than 2 millimetres (0.079 in) in diameter. There are three mechanisms of volcanic ash formation: gas release under decompression causing magmatic eruptions; thermal contraction from chilling on contact with water causing phreatomagmatic eruptions, and ejection of entrained particles during steam eruptions causing phreatic eruptions. The violent nature of volcanic eruptions involving steam results in the magma and solid rock surrounding the vent being torn into particles of clay to sand size. Volcanic ash can lead to breathing problems and malfunctions in machinery.
Volcanic lightning, while frequently observed, is not fully understood. It appears that volcanic lightning formation is somewhat analogous to thunderstorm lightning — produced by a separation of positive and negative charges from colliding materials. In thunderstorms, it is the collision of hail and rain, while in a volcano the collision of ash and solid debris particles causes the positive and negative charges to separate. The smaller and lighter negative charges tend to rise while gravity causes the heavier positive charges to fall. When the charge differential is great enough, a static electricity discharge produces the lightning.

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